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Angie Harmon (best known for her stint as an ADA on Law and Order) will appear in the season’s fourth episode, “Chuck vs. Operation Awesome” as “Sydney”, a spy for The Ring who will be out to get Ryan McPartlin’s Captain Awesome. Wait, Captain Awesome? Yep, sounds like the fan speculation was correct and this episode does indeed revolve around the newlywed Mr. Woodcomb. Just what happens to get super-spy Sydney on his trail? We’ll have to wait and see!